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AQA 6.3 / PHYSICS

Particle model of matter

Why does ice float, how do we measure a stone’s density, and why does a warm gas push harder? Use particles, practical measurements and clear calculations to find out.

Supported GCSE version · Clear examples, worked calculations and optional challenges.

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YOUR TOPIC GUIDE

Particle model of matter

Work through one section at a time. Higher-only material is labelled explicitly; optional challenges can also use Foundation content.

Words to know

Particle

An atom or molecule used as a unit in a model of matter.

Density

Mass per unit volume: how much mass fits into a given space.

Displacement

Liquid pushed aside by an object; its volume can reveal the object’s volume.

Meniscus

The curved surface of a liquid in a narrow container. Read water at the bottom of the curve.

Resolution

The smallest change an instrument can distinguish on its scale or display.

Physical change

A change that makes no new substance; reversing it restores the original material’s properties.

Sublimation

A change directly from solid to gas, without becoming liquid first.

Internal energy

The total kinetic and potential energy of all particles in a system.

Specific heat capacity

Energy needed to raise the temperature of 1 kg of a substance by 1 °C.

Specific latent heat

Energy needed to change the state of 1 kg without a temperature change.

Fusion

The solid-to-liquid change, also called melting.

Vaporisation

The change from a liquid to a gas.

Random motion

Movement in constantly changing, unpredictable directions.

System

The object or group of objects being considered.

Systematic error

An error that shifts measurements consistently, such as an incorrect zero reading.

1. Zoom in: solids, liquids and gases

A particle model helps us explain what we cannot see directly. The particles might be atoms or molecules. Start with two questions: How are they arranged? How do they move?

Particle models show a close ordered solid, a close irregular liquid and a gas with widely spaced particles.
The circles are a model, not a photograph. Particles themselves do not swell when a substance expands.
StateArrangement and movementWhat we notice
SolidClose together; vibrate about fixed positions.Keeps its shape and volume.
LiquidClose together; move past one another.Flows and takes the container’s shape.
GasFar apart; move constantly and randomly.Spreads to fill its container and is easily compressed.

2. Density: how much mass fits into a volume?

Density is mass per unit volume. Compare equal volumes: the one with the greater mass has the greater density.

Density = mass ÷ volume
ρ = m/V
ρ in kg/m³; m in kg; V in m³.

For the same substance, gas particles are much further apart than liquid or solid particles. A fixed volume of gas therefore contains fewer particles and less mass. Gases usually have much lower densities. Solids and liquids both have close particles; their densities are often similar.

Useful exception: ice is less dense than liquid water. Its particles form a more open arrangement. The water molecules do not become heavier when ice melts.

Mass against volume lines for two materials, both through the origin; material A has the steeper line.
On a mass–volume graph, a steeper line means a greater mass for each unit of volume: a greater density.
Worked example: find density and rearrange

A sample has mass 540 g and volume 200 cm³. Density = 540 ÷ 200 = 2.7 g/cm³.

To find mass: m = ρV. To find volume: V = m/ρ.

3. Choose matching units before calculating

ConversionExample
1 kg = 1000 g250 g = 0.250 kg
1 m³ = 1 000 000 cm³40 cm³ = 0.000040 m³
1 cm³ = 1 mL25 mL = 25 cm³
1 g/cm³ = 1000 kg/m³2.7 g/cm³ = 2700 kg/m³
A common trap: converting a volume is not the same as converting a length. A cube 1 m wide is 100 cm × 100 cm × 100 cm.
  1. Read the units requested in the answer.
  2. Convert the measurements if needed.
  3. Substitute into the equation and include the final unit.

4. Required practical 17: a regular solid

A rectangular metal block has a shape we can measure directly. Measure mass and volume separately.

Cuboid with measured dimensions 5.0 by 3.0 by 2.0 centimetres and a balance reading 240.0 grams.
Use the dimensions to calculate volume. The balance reading gives mass, not density.
  1. Zero the balance and measure the block’s mass.
  2. Measure length, width and height. Use a ruler, Vernier callipers or a micrometer as appropriate. Check for a zero error.
  3. For a cuboid, calculate V = length × width × height.
  4. Calculate density from mass ÷ volume. Repeat measurements and compare values.

Improve the result: measure small dimensions with finer-resolution equipment. Measure at several positions if the block is not perfectly even. Repeats reveal variation; they do not automatically remove a zero error.

5. Required practical 17: an irregular solid

A stone has no simple length × width × height volume. Instead, measure the water it displaces when submerged.

Measuring cylinder readings rise from 40 to 65 cubic centimetres when an irregular solid is fully submerged.
Object volume = final reading − starting reading. Read the bottom of the curved water surface at eye level.
  1. Measure the dry object’s mass on a balance.
  2. Record the starting water volume.
  3. Lower the object carefully until fully submerged. Remove trapped air bubbles and record the new volume.
  4. Subtract the two readings, then calculate density.
Another method: fill a displacement can to its spout and let excess water finish dripping. Submerge the object and collect the displaced water in a measuring cylinder. Its volume equals the object’s volume.

Use a solid that does not dissolve or react with the liquid. Avoid splashing. Trapped bubbles make the measured volume too large, giving a density that is too small.

6. Required practical 17: a liquid

The balance also measures the container. We must subtract its mass to find the liquid’s mass.

An empty measuring cylinder has mass 80.0 grams; the same cylinder with 50 cubic centimetres of liquid has mass 125.0 grams.
Subtract the empty container mass before dividing by the measured liquid volume.
  1. Measure the mass of a clean, dry measuring cylinder.
  2. Add the liquid; read its volume at eye level.
  3. Measure the cylinder plus liquid.
  4. Subtract to find liquid mass, then calculate density.

A balance can be tared with the empty cylinder on it, so it displays liquid mass directly. Use a suitable cylinder scale, wipe liquid from the outside, and keep the balance dry.

7. Changing state: same substance, same mass

Melting ice makes liquid water, not a new substance. If the water freezes, it recovers the properties of ice. This makes it a physical change.

Arrows connect solid, liquid and gas through melting, freezing, boiling or evaporation, condensation and sublimation.
Sublimation skips the liquid stage. Reverse changes recover the original substance.
ProcessWhat changes?
BoilingLiquid becomes gas throughout the liquid at its boiling point.
EvaporationParticles escape from the liquid surface; this can happen below the boiling point.
SublimationA solid changes directly into gas.

Mass is conserved: the same particles are still present during a change of state. In an open beaker, the balance reading may fall when gas escapes. The total mass of beaker contents plus escaped gas is unchanged.

8. Internal energy is more than temperature

Internal energy is the total kinetic energy and potential energy of all the particles in a system.

Two panels distinguish particle motion energy from energy associated with positions and interactions.
Temperature is related to average kinetic energy. Internal energy is the total for all particles, including their potential energy.
  • Kinetic energy: particles have energy because they move or vibrate.
  • Potential energy: energy is associated with particle positions and interactions.
  • Heating: transfers energy into the system. It may raise temperature, cause a change of state, or both in successive stages.
Two samples can have the same temperature but different internal energies. A larger sample of the same material, in the same state, contains more particles.

9. Warming a substance: specific heat capacity

Specific heat capacity, c, is the energy needed to raise the temperature of 1 kg of a substance by 1 °C, without a change of state.

Equal one-kilogram blocks receive 900 joules; specific heat capacities 900 and 450 joules per kilogram degree give rises of one and two degrees.
The temperature rise depends on energy supplied, sample mass and the material’s specific heat capacity.
ΔE = mcΔθ
Energy change ΔE in J; mass m in kg; specific heat capacity c in J/(kg °C); temperature change Δθ in °C.
Worked example: heating 250 g of water
  1. Mass: 250 g = 0.250 kg.
  2. Temperature rises from 18 °C to 30 °C: Δθ = 12 °C.
  3. Using c = 4200 J/(kg °C), ΔE = 0.250 × 4200 × 12 = 12 600 J.

Rearrangements: c = ΔE/(mΔθ); Δθ = ΔE/(mc).

For the same energy input, a smaller mass or a smaller c gives a bigger temperature rise. This is the same relationship used in the Energy worksheet; required practical 14 is covered there.

10. Changing state: specific latent heat

Specific latent heat, L, is the energy needed to change the state of 1 kg of a substance without changing its temperature.

Ice at zero degrees becomes water at zero degrees, then water at twenty degrees, with the relevant equations below.
Use latent heat for a change of state; use specific heat capacity for a temperature change.
QuantityChangeUnit
Specific latent heat of fusionSolid ↔ liquidJ/kg
Specific latent heat of vaporisationLiquid ↔ gasJ/kg
E = mL
E in J, m in kg, L in J/kg.
Rearrange: L = E/m or m = E/L.
Worked example: melting ice already at 0 °C

Mass = 0.20 kg; L of fusion = 334 000 J/kg.
E = 0.20 × 334 000 = 66 800 J.

This energy melts the ice. It does not also warm the resulting water. Freezing the same mass releases the same energy under these conditions.

During melting or boiling, energy changes particle arrangement and potential energy. Average kinetic energy, and therefore temperature, stays constant during the change of state of a pure substance at constant pressure.

11. Read a heating or cooling graph

Read the axes first. A rising line means temperature increases. A flat section can show a change of state while energy is still being transferred.

Heating curve with labelled points A to F, a zero-degree plateau from B to C and a hundred-degree plateau from D to E.
This idealised water graph assumes constant pressure. Heating continues, but its rate need not be constant; the lengths of sections are illustrative.
SectionWhat is happening?
A–BSolid warms; average particle kinetic energy increases.
B–CMelting; solid and liquid are both present.
C–DLiquid warms.
D–EBoiling; liquid and gas are both present.
E–FGas warms.

For cooling, follow the changes in reverse: temperature falls between changes of state; energy is released during condensation or freezing at constant temperature.

A flat line alone does not prove a change of state. Check the context: energy must still be supplied or removed, and the sample must be at a transition temperature.

12. Gas pressure: tiny collisions, a measurable force

Gas particles are in constant random motion. When they hit a container wall, they exert a force. The combined effects of many collisions produce gas pressure.

Two equal rigid containers contain the same number of gas particles; motion indicators are longer for the hotter gas.
Compare at fixed volume. Heating increases average kinetic energy and therefore average speed.
  1. The gas temperature increases.
  2. Particles have greater average kinetic energy and move faster.
  3. They hit the walls more often and each collision produces a larger change in momentum.
  4. The average force on the walls increases, so pressure increases.

Cooling a fixed amount of gas at constant volume has the opposite effect. Not every particle has the same speed: temperature is related to the average kinetic energy.

Do not say particles get bigger, multiply or stop moving when cooled. This comparison keeps both the amount of gas and its volume constant. Never heat a sealed container as a home experiment.